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Computational and Experimental Investigations Concerning Rare Gas and DPAL Lasers and a Relaxation Kinetics Investigation of the Br2 + 2NO = 2BrNO Equilibrium
Schmitz, Joel R.

2017, Master of Science (MS), Wright State University, Chemistry.
This research contains four different research projects, the first an educational project introducing hydrogen bromide and deuterium bromide (HBr/DBr) and carbon monoxide (CO) as viable options for infrared vibration-rotation spectroscopy at 0.125 cm-1 or 0.5 cm-1 resolution in the teaching laboratory. The second project involved determining the spectral shifts of lanthanide fibers for diode-pumped alkali laser (DPAL) applications. Spectral shifts of lanthanides were determined using UV-VIS-NIR absorbance spectroscopy and laser-induced fluorescence (LIF). The third project entailed computing Ar* atomic energy levels and the potential energy curves of Ar*+He laser systems arising from 3p54s1 and 3p54p1 Ar* electronic configurations using ab initio theory. The final project of this research determined rate coefficients and the equilibrium constant of the formation of nitrosyl bromide (BrNO) using relaxation kinetics. Integrated solution of the relaxation rate equation and third-order integrated rate law methodologies produced final values of kf = 1.50(6) x 10-5 torr-2s-1, kr = 5.8(8) x 10-5 torr-1s-1, and Keq = 0.26(3) torr-1, agreeing with literature within uncertainty.
David Dolson, Ph.D. (Advisor)
Rachel Aga, Ph.D. (Committee Chair)
Amit Sharma, Ph.D. (Committee Member)
Paul Seybold, Ph.D. (Committee Member)
159 p.

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Schmitz, J. (2017). Computational and Experimental Investigations Concerning Rare Gas and DPAL Lasers and a Relaxation Kinetics Investigation of the Br2 + 2NO = 2BrNO Equilibrium. (Electronic Thesis or Dissertation). Retrieved from https://etd.ohiolink.edu/

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Schmitz, Joel. "Computational and Experimental Investigations Concerning Rare Gas and DPAL Lasers and a Relaxation Kinetics Investigation of the Br2 + 2NO = 2BrNO Equilibrium." Electronic Thesis or Dissertation. Wright State University, 2017. OhioLINK Electronic Theses and Dissertations Center. 22 Sep 2017.

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Schmitz, Joel "Computational and Experimental Investigations Concerning Rare Gas and DPAL Lasers and a Relaxation Kinetics Investigation of the Br2 + 2NO = 2BrNO Equilibrium." Electronic Thesis or Dissertation. Wright State University, 2017. https://etd.ohiolink.edu/

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