Master of Science in Engineering, Youngstown State University, 2024, Department of Civil/Environmental and Chemical Engineering
The 108-mile-long Mahoning River, historically one of the most contaminated rivers in the U.S., contains metals above the EPA aquatic criteria. This study identifies the contamination levels, spatiotemporal patterns, sources, speciation, and bioaccessibility of metals (As, Ba, Fe, Pb, Ni, Zn) in the water and sediment of the lower Mahoning River. Sediment analysis showed that all metals exceeded the Sediment Reference Value, except for Ba. Regression analysis showed a significant decrease of Pb and Fe (p < 0.05) in water from 1993-2021, suggests that the water quality of the river with respect to Pb and Fe is improving comparatively in the past three decades. The contamination factor indicated that metals in water were uncontaminated (< 1), while metals in sediment were moderately to highly polluted (3-15). Inverse distance weighting in sediments illustrated decreasing concentrations towards downstream for Ni, while increasing concentrations towards downstream for As, Ba, Fe, Pb, and Zn in sediment. The inverse distance weighting patterns may be associated with land use, as the river traversed the agricultural region upstream, the urbanized region downstream, and mixed-land areas in the last stretch. Speciation analysis revealed metals in water and sediments were in divalent forms (HM2+), except Pb (PbOH+, PbCO3), indicating high bioaccessibility and potential plant uptake in the aquatic environment.
Committee: Sahar Ehsani PhD (Advisor); Felicia Armstrong PhD (Committee Member); Rick Deschenes PhD (Committee Member); Bradley Shellito PhD (Committee Member)
Subjects: Environmental Education; Environmental Engineering; Environmental Geology; Environmental Science; Environmental Studies; Geographic Information Science