Master of Science, The Ohio State University, 2022, Earth Sciences
Despite efforts to mitigate and reduce contamination of surface water resources, water quality remains impaired in many places worldwide, primarily due to nonpoint source pollutants including agriculture and urbanization. These both introduce excess sediment and nutrients, various types of chemicals, and more to surface waters. The Scioto River in the Upper Scioto River Basin in central Ohio was studied to assess the influence of large-scale agriculture and urbanization/suburbanization on river geochemistry. The Scioto River has its headwaters in land dominated by row-crop agriculture, then flows through the expanding metropolitan Columbus area, then again through suburbs and agricultural land south of downtown Columbus. Additionally, the river is dammed in two places, providing another means of assessing how modification of natural river systems impacts river geochemistry.
The Scioto River was sampled in five locations with varying degrees of surrounding agricultural and urban land use. Samples were collected weekly at three locations from February 2021 to August 2021, then monthly through December 2021. The other two locations were sampled monthly for the entire study period. Samples were analyzed for major ions, nutrients, select trace elements, and stable water isotopes. Results revealed that concentrations of many analytes were generally highest at the most upstream location, decreased until downtown Columbus, and increased at the location furthest downstream. Because much of the study area is underlain by carbonate bedrock, correlations with Ca and/or Mg were thought to indicate a primarily geogenic source of the solute. Elements with moderate to strong positive correlations with Ca and/or Mg included Na, HCO3, Cl, SO4 F, Br, Li, U, Ni, Rb, Mo, Ba, and Sr. Additionally, many of these elements had moderate to strong negative correlations with NO3+NO2, which is primarily from agricultural inputs. Further, log C – log Q relationships of these data revealed c (open full item for complete abstract)
Committee: W. Berry Lyons (Advisor); Thomas Darrah (Committee Member); Nicholas Basta (Committee Member); Susan Welch (Committee Member)
Subjects: Earth; Environmental Geology; Environmental Science; Geology; Hydrologic Sciences; Hydrology