PHD, Kent State University, 2019, College of Arts and Sciences / Department of Physics
The main goal of this research is to study the surface properties of liquid-vapor and liquid-liquid-vapor interfaces with high precision using the technique of surface light scattering spectroscopy (SLSS), which measures the power spectrum of light scattered from thermally generated capillary waves with an rms height ~1 nm. This power spectrum depends on both surface and bulk properties of the fluid, including surface tension and bulk viscosity, allowing the inference of the values of these and perhaps other parameters. In this dissertation, I focus on the surface tension and bulk viscosity associated with a liquid. Innovative optical design has increased signal and signal-to-noise ratio. This enhances measurement accuracy over the entire range of wave numbers, while enabling measurements at higher wave numbers above 1500/cm.
After refining the apparatus and technique as much as possible, I apply it to a sequence of systems. (a) Simple Fluids: Standard materials including acetone, pentane, methanol and water serve to calibrate and validate the SLSS technique and experimental protocol. (b) Highly viscous fluids, relevant for capillary-driven fluid management to control propellant transfer in space flight. We explore the regime between the overdamped and underdamped cases, which have been difficult to characterize with SLSS, using well-characterized glycerol/water mixtures. (c) Mixtures: Measurements of pentane/2-methylpentane mixtures prepare for an upcoming NASA microgravity experiment to optimize the effectiveness of wickless heat pipes. (d) Thin organic films on water: coupling between upper and lower interfaces of a thin film allows the study of Casimir-Polder forces and measurement of the onset of wave mode transitions, for example, peristaltic suppression. (e) Molecularly thin films on water: thin films of a smectic liquid crystal on water have many applications, directly as biosensors, and indirectly, to develop a better understanding of alignment laye (open full item for complete abstract)
Committee: Elizabeth Mann (Advisor)
Subjects: Physics