Doctor of Philosophy, The Ohio State University, 2023, Materials Science and Engineering
Rising concerns related to fuel consumption and greenhouse emissions are being addressed by the automotive industry through vehicle lightweighting. Hence to meet the stringent requirements for lightweighting, conventional steel body parts are being replaced with Al alloys, Mg alloys and composite materials. However, the use of dissimilar materials together poses a serious threat of galvanic corrosion leading to accelerated degradation of galvanically coupled body parts. Aiming to develop the automotive closure panels using carbon fiber reinforced plastics (CFRP) inner and an outer aluminum alloy sheet to replace what is now an all-steel design, corrosion studies are performed to determine effective qualification of materials.
In the first part of this project, CFRP materials of two types, named as twill and random, coupled with aluminum alloys (AA) 6111 and 6022 in all combinations, are subjected to a Ford laboratory accelerated cyclic corrosion test (CETP: 00.00-L-467) and on-road testing with the help of OSU campus buses for a year. The ability of the laboratory accelerated test to predict the on-road corrosion behavior is assessed by comparing the material volume loss determined using optical profilometer, microscopic images of corroded regions, and measurements of galvanic currents of the coupons exposed to the cyclic test. Analysis of the test results indicated that the coupon combination AA6111 and CFRP-random exhibits the highest corrosion susceptibility whereas AA6022 coupled with CFRP-twill is least susceptible to galvanic corrosion among the combinations used in this study.
In the second part of the study, electrochemical behavioral differences between CFRP-twill and -random contributing to the differences in activities when coupled to AA6xxx are evaluated. For this, a copper deposition technique was developed to quantify the extent of electrochemical activity and identify the exact location of electrochemically active sites on the CFRP. Optimization (open full item for complete abstract)
Committee: Gerald S. Frankel Dr. (Advisor); Narasi Sridhar Dr. (Committee Member); Jenifer Locke Dr. (Committee Member)
Subjects: Atmosphere; Conservation; Energy; Engineering; Materials Science; Sustainability; Transportation