Master of Science, The Ohio State University, 2015, Civil Engineering
The work presented in this thesis builds upon previous research related to the biodegradation of organic constituents within hydraulic fracturing fluids (HFF). Hydraulic fracturing fluids, which contain approximately 1% chemical additives, are injected into deep shale plays to create cracks and improve the mobility and extraction of oil and natural gas. Although these fluids contain mostly organic compounds that are considered readily biodegradable as individuals, complex surfactant and glycol formulations are also used within these fluids to function as emulsifiers and wetting agents and may take longer to degrade in environmental systems. There are multiple routes where hydraulic fracturing fluids may be released to shallow subsurface and groundwater aquifers via spills or equipment failures and there is a large concern and uncertainty as to how the organic constituents within HFF will attenuate. If chemical additives within HFF, specifically surfactants, are accidently released to the environment and enter a groundwater aquifer that is used for drinking water, understanding the recalcitrance of these compounds is crucial in assessing the risk to public health. Here, analysis of the anaerobic biodegradation of glycol formulations, in addition to other nonionic surfactants, was conducted using batch soil and groundwater microcosms. Microcosms were used to test the degradation of five HFF related substrates: (1) a synthetic fracturing fluid (SFF) (2) a revert flow stimulation surfactant (3) a corrosion inhibitor (4) polypropylene glycol (PPG), and (5) propylene glycol. Changes in dissolved organic carbon (DOC), surfactant concentration (PPG, C8 and C10 ethoxylated alcohols, nonylphenol ethoxylates), metabolite concentration (propylene glycol, n-propanol, propionaldehyde, propionate, acetone, acetate) and other geochemical parameters (total and ferrous iron, sulfate, sulfide, and chloride) were measured over 50 days. Microbial community analysis and (open full item for complete abstract)
Committee: Paula Mouser (Advisor); Gajan Sivandran (Committee Member); John Lenhart (Committee Member)
Subjects: Environmental Engineering; Environmental Science