Master of Science (M.S.), University of Dayton, 2024, Materials Engineering
If gone undetected, volcanic ash in the atmosphere can have significant negative effects on
the performance of air-breathing gas turbine engines. When ingested into the front of the
engine, abrasion and erosion of key mechanical components can occur, accompanied by
degradation of the materials located in the late-stages of the engine by ash that has become
molten due to the high-temperature environment. These phenomena can lead to significant
damage and premature failure in a fielded gas-turbine engine, thus the need to evaluate
engine materials prior to their implementation arises. While volcanic ashes and turbine
engine materials have been studied extensively in the literature, they have largely been
studied independently, therefore no standardized volcanic ash media to be used in materials
testing has been developed. In this work, a group of natural volcanic ash samples were
evaluated using a variety of techniques to understand their chemical, physical, and thermal
behavior. The information gathered in the characterization of the group of natural ash
samples was then used to develop a synthetic volcanic ash media that has similar chemistry
to and behaves like a natural ash when exposed to an environment like that in a late-stage
gas turbine engine. The new synthetic ash media was compared to a natural ash, from Mt. Mazama in Oregon, USA. Specifically, its ability to melt and infiltrate the microstructural
features of 7% yttria-stabilized zirconia thermal barrier coatings deposited on superalloy
coupons was examined. It was shown via SEM analysis that when heated to 1200 °C, the
synthetic ash melts and infiltrates the thermal barrier coating within a comparable time
(<30 minutes) as Mt. Mazama ash, leading to the conclusion that it can be deemed an
effective replacement for natural volcanic ash in materials testing. The development of this
synthetic ash test media is meant to provide a solid starting point for future development
of medias used (open full item for complete abstract)
Committee: Li Cao Ph.D. (Committee Chair); Matthew Hartshorne Ph.D. (Advisor); Donald Klosterman Ph.D. (Committee Member)
Subjects: Aerospace Materials; Chemistry; Earth; Engineering; Geology; High Temperature Physics; Materials Science; Mineralogy