Doctor of Philosophy, The Ohio State University, 2022, Chemical Engineering
Drag reduction (DR) by additives typically involves the use of either high molecular weight polymer or surfactants, and can reduce turbulent pressure losses in pipes by up to 90%. These additives, particularly high polymers, have seen considerable use in increasing the throughput of crude oil pipelines. Surfactant additives, while even more effective than their polymer cousins, have not seen widespread adoption despite their applicability to recirculating district heating or cooling networks.
Due to their effects on the turbulent structure of pipe flow, drag reducing additives also result in the loss of radial mixing, and thus the suppression of convective heat transfer. This is referred to as the 'heat transfer reduction' (HTR) effect. Under normal conditions, drag reducing additives can reduce convective heat transfer in even greater amounts than they do turbulent pressure losses. Much of the recent research in the field of surfactant drag reduction has, therefore, been dedicated to the mitigation of heat transfer reduction. In this work, two projects are presented which successfully achieve this goal.
In the first, a constricted heat exchanger is used to locally increase the shear stresses experienced by the working fluid. Simultaneously, a `weak' drag reducing solution comprised of quaternary ammonium salts with saturated tails 16 and 14 carbons in length and the counterion 3-chlorobenzoic acid. In conjunction with the constricted heat exchanger, this mixture is able to simultaneously generate high (>60%) DR and low (>30%) HTR over a range of flow rates and temperatures. Other unique properties of the system are examined, including switchability and hysteresis.
The second study involves the design and application of 'gentle' static mixers. Rather than being designed to destroy the micellar structure thought to be responsible for DR, these mixers are intended to periodically disrupt the thermal boundary layer in the heat exchanger, thus improving heat tr (open full item for complete abstract)
Committee: Kurt Koelling (Advisor); Jim Rathman (Committee Member); Stuart Cooper (Committee Member); Andrew Maxson (Committee Member)
Subjects: Chemical Engineering; Energy; Engineering; Fluid Dynamics