Doctor of Philosophy, The Ohio State University, 2021, Nuclear Engineering
Semiconductor gamma ray detectors are highly demanded in numerical fields of applications, such as homeland security, industry, medical imaging and academic research. As the golden standard of gamma spectroscopy, the High Purity Germanium (HPGe) detector has an energy resolution of less than 0.5% Full-Width-Half-Maximum (FWHM) at 662 keV. However, HPGe detector needs liquid nitrogen cooling due to its small energy bandgap. As the only commercially available room temperature gamma ray detector, the Cadmium-Zinc-Telluride (CdZnTe) detector achieves an energy resolution of less than 1% FWHM at 662 keV. Nevertheless, the growth issues and the associated high cost of the CdZnTe detectors continue to drive the search for alternative radiation detection materials featuring low-cost growth methods.
Recently, the lead (Pb) halide perovskites emerged as a promising candidate for hard radiation detection due to their favorable properties, such as high atomic number, large mobility-lifetime product, wide and tunable energy bandgap. In this research, we evaluated the performance of perovskite gamma ray and X-ray detectors, especially the inorganic CsPbBr3 single crystals made from low-cost solution grown method. The design principles of a gamma ray detector architecture were studied. The leakage current reduction performance of different detector structures, that is, Ohmic-Ohmic, Schottky-Ohmic, Schottky-Schottky, were compared theoretically. The role of Electron/Hole Transport Layers in a gamma ray detector was discussed. Processing sequences for CsPbBr3 detector fabrication were developed. Through well controlled surface processing, the leakage current as low as less than 5 nA at -200 V was consistently achieved, which is comparable to a CdZnTe detector. The investigation of perovskite detector architecture and development of detector processing sequences pave the way of effective design and fabrication of CsPbBr3 detector with consistent performance. The X-ray and alpha part (open full item for complete abstract)
Committee: Lei Cao (Advisor)
Subjects: Nuclear Engineering