Doctor of Philosophy, University of Akron, 2019, Mechanical Engineering
Chi Ma, University of Akron, May 2019. Improving the plasticity of metallic glass through heterogeneity induced by electropulsing-assisted surface severe plastic deformation. Advisor: Yalin Dong. Co-advisor: Chang Ye.
Metallic glasses have raised tremendous interests to industrial and academic community due to its superior properties (e.g. ultimate strength, wear resistance, and soft-magnetic property) since their invention. The amorphous structure, on the one hand, gives rise to advanced material properties while, on the other hand, causes poor ductility hindering the wide application of metallic glasses. Aiming at designing ductile metallic glasses, this thesis research investigates surface severe plastic deformation (SSPD), electropulsing, and their combined treatment to achieve the transition from brittle to ductile, and unveil the relationship between microstructure and mechanical deformation behavior through molecular dynamics simulation and fracture theory.
Ultrasonic nano-crystal surface modification (UNSM), as a member of the SSPD family, is a recent developed technology possessing high controllability and good surface finish. By applying ultrasonic mechanical peening, UNSM leads to the dilation of local atomic structure and thus induces extra free volume heterogeneously. Extra free volume is generated after UNSM treatment and consequently plasticity, i.e. yielding and more plastic strain, starts to appear. The observation of fracture surface suggests that
before fracture occurs, higher density of shear bands exists in the UNSM-treated samples and severe interaction between shear bands impedes propagation of themselves, which contributes to material plasticity.
In addition to extra free volume, the secondary crystalline phase induced by UNSM and its effect on increasing plasticity is also explored. In this thesis, for the first time, the composite structure of nanocrystalline phase co-existed with extra free volume is fabricated by electropulsing-ass (open full item for complete abstract)
Committee: Yalin Dong PhD (Committee Chair); Chang Ye PhD (Committee Co-Chair); Guo-Xiang Wang PhD (Committee Member); Rajeev Gupta PhD (Committee Member); Jun Ye PhD (Committee Member); Kwek-Tze Tan PhD (Committee Member)
Subjects: Materials Science; Mechanical Engineering; Metallurgy; Molecular Physics; Molecules; Nanotechnology