Master of Science (MS), Bowling Green State University, 2024, Physics
Cd(Se,Te) has emerged as a leading choice for commercial thin-film PV devices, owing to
their lower cost of production, high energy yields, and low degradation rates compared to silicon
technology. Despite significant advancements, Cd(Se,Te) cells suffer from recombination losses,
reducing the open-circuit voltage (Voc). This thesis aims to identify, distinguish, and quantify
recombination losses and their locations within Cd(Se,Te) solar cells via temperature and light
intensity-dependent current-voltage (JVTi) analysis. Cd(Se,Te) solar cells were modeled using
COMSOL Multiphysics, simulating parameters such as temperature (T ), light intensity (i), front
surface recombination velocity (Sf), back surface recombination velocity (Sb), bulk lifetime (τ ),
conduction and valence band offset (CBO and VBO at heterojunctions), and back contact
Schottky barrier height (Φbp). Additionally, graded and uniform selenium devices were studied,
and ZnTe:Cu was investigated as a back contact interface.
In this work, recombination activation energies, Ea, from JVTi studies were shown to
quantify the front interface conduction band offset losses when the interface band gap is smaller
than the bulk band gap and when front interface recombination dominates. If the Ea equals the
bulk band gap, then Voc losses may occur at the front interface or within the bulk. When the front
surface recombination and bulk lifetime are moderately low, a transition from front surface (low
Ea) to bulk (higher Ea) mechanisms can be observed with increasing light intensity, i. Back
surface recombination has negligible effects on Voc for the device parameters specified herein.
Comparison of Cd(Se,Te) JVTi data provided by NREL to simulations in this work indicates that
front surface recombination dominates Voc losses for Sf = 103 cm/s and CBO = -0.2 eV for that
particular device. Adjusting the band alignment to CBO = 0 eV and reducing Sf would
significantly increase Voc.
Committee: Marco Nardone (Committee Chair); Mikhail Zamkov (Committee Member); Alexy Zayak (Committee Member)
Subjects: Physics