PHD, Kent State University, 2011, College of Arts and Sciences / Department of Physics
In addition to the simple calamitic mesogens, having cylindrically symmetric shape, there are more complex molecular associations formed by bridging of two molecules, e.g., via hydrogen bonding, that exhibit liquid crystal phases. In this dissertation research mesomorphic properties of two compounds namely, 4-[2, 3, 4-tri(octyloxy)phenylazo] benzoic acid (TOPAB) and 4-[2, 3, 4-tri(heptyloxy)phenylazo] benzoic acid (THPAB) and their mixtures with two simpler hydrogen bonding mesogens, 4-(4-octyloxy)benzoic acid (OOBA) and 4-(4-decyloxybenzoyloxy)benzoic acid (DBBA), were investigated using differential scanning calorimetry, polarizing optical microscopy, capacitance measurements, conoscopy, polarized Raman spectroscopy, and synchrotron x-ray scattering.
Unusual x-ray scattering results, which prompted this investigation, are very different from other calamitic nematic phases. The small and large angle x-ray peaks are in the same direction while they are normally orthogonal to each other. Furthermore, similar materials have previously been considered as good candidates to exhibit the biaxial nematic phase. Contrary to normal expectations, x-ray results are not consistent with simple linear H-bonded dimer formation, as one normally would expect. In order to adequately explain the x-ray results, it is necessary to assume that oblique molecular associations in which the mesogens H-bond at approximately 67o and take on an average shape resembling a bent-core mesogen. Other techniques were employed to test if this was indeed the case and to determine if the system possessed biaxial order fluctuations or formed the biaxial nematic phase. Nematic uniaxial orientational order parameters P200 and P400 determined from x-ray diffraction and Raman measurements for TOPAB are in very good agreement: P200 = 0.52 – 0.68 and P400 = 0.12 – 0.30 from X-ray scattering; and P200 = 0.48 – 0.75 and P400 = 0.25 – 0.48 from Raman scattering.
Capacitance and electro-optical measurements suppo (open full item for complete abstract)
Committee: Satyendra Kumar (Advisor)
Subjects: Condensed Matter Physics