Doctor of Philosophy, University of Toledo, 2016, Chemical Engineering
Declining nonrenewable petroleum resources combined with political and environmental concerns over fossil fuels have necessitated the search for alternate energy sources. Plant (lignocellulosic) biomass, which includes the fibrous, woody, and generally inedible portion of plant matter, is an abundant, inexpensive, and sustainable source of organic carbon that can be processed to produce fuel ethanol and a variety of other chemicals. The biological conversion of cellulosic biomass to ethanol could offer high yields at low costs, but only if more improvement is seen in technology for releasing simple sugars from recalcitrant biomass. Lignocellulosic biomass is composed of three major components- cellulose, hemicellulose, and lignin. The cellulose and hemicellulose portions when hydrolyzed into glucose and pentose sugars, can be fermented to produce fuel. The pretreatment of biomass is a crucial step, and in recent years, ionic liquids (ILs) have been gaining recognition as environmentally benign solvents for biomass pretreatment, owing to their favorable properties Although a promising route, IL pretreatment still harbors several critical aspects that require further investigation, and the goal of this dissertation is to address these concerns.
A key aspect that influences the economic viability of the ionic liquid pretreatment technique is the recovery and reuse of ILs. The extent of recovery of the IL under investigation, 1-ethyl-3-methylimidazolium acetate (EMIM-Ac), is investigated and the results are presented in chapter 3. It is shown that the ionic liquid does not irreversibly adsorb onto the biomass and can be recovered in the displacement solvent (water is used as antisolvent for separating ionic liquid from the biomass after pretreatment) at different biomass loadings. Nearly complete recovery of IL in wash solutions is achieved and no appreciable loss in its effectiveness for subsequent pretreatment is observed for over 9 recycle stages. However, the water (open full item for complete abstract)
Committee: Sasidhar Varanasi (Committee Chair); Jared Anderson (Committee Member); Bryant Hanson (Committee Member); Glenn Lipscomb (Committee Member); Constance Schall (Committee Member)
Subjects: Chemical Engineering