Doctor of Philosophy (PhD), Ohio University, 2018, Chemical Engineering (Engineering and Technology)
Nowadays, the development of energy-efficient processes for the treatment of wastewater is becoming an essential research field; taking into account the projected global population rise, the depletion of fresh water, and the necessity for available and renewable sources of energy. Within this context, the electro-oxidation of ammonia has been received considerable and increasing attention due to its advantageous in deammonification of wastewater and at the same time, production of pure hydrogen as a source of energy. However, the performance of this process should be optimized prior to wide industrial utilization.
There are several factors that affect the performance of ammonia electrolysis. These factors can be divided into macro scale (like flowrate, concentration) and micro scale (like electrodes material and morphology). The effects of these factors can be evaluated in a mathematical model which would be able to optimize the process. Optimization of the process results in widely and commercially usage of ammonia electrolyzers. In this electrolyzer, water reduces at the cathode, while ammonia oxidizes at the anode. Hydrogen evolution reaction (HER) at the cathode can proceed on transition metals like nickel. However, ammonia oxidation needs noble metals like platinum to proceed; one of the other hindrances of widely commercialization of this process. This problem can be solved if the knowledge of the process kinetics and mechanism of the reaction on the surface of the catalyst clarified.
The first part of this research focused on developing a mathematical model using flow regime, transport equations, the ammonia oxidation kinetics on platinum at the anode and the hydrogen evolution kinetics on nickel at the cathode. All of the non-linear differential equations were solved by finite difference methods in a comprehensive FORTRAN code. The model showed both qualitative and quantitative agreement with experimental measurements which were carried on in a bench s (open full item for complete abstract)
Committee: Gerardine Botte (Advisor); Valerie Young (Committee Member); Howard Dewald (Committee Member); Nancy Sandler (Committee Member); Kevin Crist (Committee Member)
Subjects: Chemical Engineering; Environmental Engineering; Experiments