PhD, University of Cincinnati, 2016, Engineering and Applied Science: Chemical Engineering
Nanotechnology has undergone a dramatic increase in popularity in the last decade due to the unique physicochemical characteristics of engineered nanomaterials (ENMs). Currently, approximately a quarter of all nano-enabled consumer products contain silver nanoparticles (AgNPs). AgNPs are incorporated into a wide range of consumer products (e. g., textiles, filters, disinfectants, and washing machines) and have a wide range of medical, industrial and scientific applications.
The increased application of AgNPs will inevitably lead to their release into environmental systems. Since the presumed mechanisms governing the fate, transport and toxicity of matter at the bulk scale may not directly apply to nanomaterials, the potential environmental impacts associated with the release of AgNPs must be evaluated. Furthermore, AgNPs are manufactured with a wide range of physicochemical properties that impact their fate, transport and toxicity in the environment.
To this end, the impact of silver nanoparticles on the composting of municipal solid waste was evaluated. Neither the presence of AgNPs nor the presence of Ag+ had a statistically significant influence on leachate, gas and solid quality parameters, and therefore, on overall composting performance. However, AgNPs and Ag+ both changed the overall structure of the bacterial communities within the compost. Nevertheless, the functional performance of the composting process was not significantly affected due to the abundance and functional redundancy of the bacterial communities within the compost samples. While surface transformations of AgNPs to AgCl and Ag2S reduce toxicity, complexation with organic matter may also play a role. The results of this study further suggest that at relatively low concentrations of AgNPs, these organically rich waste management systems can withstand the presence of AgNPs.
The microbial toxicity of silver nanoparticles stabilized with different capping agents were evaluated under anaer (open full item for complete abstract)
Committee: Stephen Thiel Ph.D. (Committee Chair); Thabet Tolaymat Ph.D. (Committee Member); Vadim Guliants Ph.D. (Committee Member); Vesselin Shanov Ph.D. (Committee Member); George Sorial Ph.D. (Committee Member)
Subjects: Chemical Engineering