Doctor of Philosophy, Case Western Reserve University, 2017, Materials Science and Engineering
The construction of mesoscale assemblies using a bottom-up approach is an emerging research area in recent years, while understanding the interactions that control the organization of the constructing building blocks turns out to be a prerequisite for effective assembly design. The intrinsic electronic structures of materials determine their optical properties, which give rise to long-range interactions including electrostatic and van der Waals (vdW) components. And electrostatic along with vdW interactions, are the fundamental interactions that drive mesoscale assembly. In this research, the long range interactions of inorganic material and bio-molecules are investigated using both
experiment and computation optical methods, and then a functional mesoscale assembly based on an inorganic substrate and biomolecular particles are built. In terms of the inorganic material, the full spectral optical properties and van der Waals-London interaction of bulk SiC crystal is investigated with a combination of vacuum ultraviolet
spectroscopy and Liftshiz theory-based Hamaker coefficient calculation, and compared with OLCAO electronic structure calculations of the band structure and ab initio optical properties of SiC. Cylindrical biomolecules, DNA, is selected as a biomolecular example. The effect of nitrogen base polarizability on the optical properties and electronic
structures of double-strand DNA are studied by optical characterization and ab initio density functional theory modeling; then G-quadruplex DNA consisting of human telomere sequence are characterized by spectroscopy, static light scattering and ab initio modeling, and compared with corresponding double-strand DNA, giving rise to the
structural dependent electronic structures and pH dependent pair-wise interactions. Finally, the first semi-ordered, layered, mesoscale self-assembly capable of photon management comprised of plant viruses is created and characterized. Anti-reflection and photon-trapping properti (open full item for complete abstract)
Committee: Roger French Dr. (Advisor); Nicole Steinmetz Dr. (Committee Member); Alp Sehirlioglu Dr. (Committee Member); Rudolf Podgornik Dr. (Committee Member); Hongping Zhao Dr. (Committee Member)
Subjects: Materials Science