MS, University of Cincinnati, 2022, Engineering and Applied Science: Aerospace Engineering
The gas phase pyrolysis method, also called the floating catalyst method, has the potential to provide carbon nanotube (CNT) materials such as sheet, tapes, and yarn at an industrial scale. However, refinement and scale up of the process is still needed to put CNT materials into everyday applications. Experimentation is being performed around the world to increase the properties of CNT materials and to increase the efficiency and output of the floating catalyst process. This experimentation is based mostly on trial and error. But trial and error have limitations in optimizing the process because many variables are involved in the process, experimentation is expensive, and setting up the synthesis reactor is a manual and time-consuming process. Many experiments are required to try to determine the flow characteristics, temperature profiles, reactor size, tube material, and many process variables that will improve the quality and the yield of the CNT web or sock produced. Moreover, different research groups around the world report somewhat different approaches and end results from their specific processes, and it is difficult to rationalize all the different results. Clearly, a more efficient approach is needed to improve the gas phase synthesis method. Especially upscaling the production process will require accurate predictive analysis before companies invest large funding into mass production of CNT materials. Ideally, a way of trying various flowrates, changing the configuration of the hot zone, the injector position, and many other variables without manually reconfiguring the reactor setup each time is needed. Therefore, this thesis developed a computational simulation solution, through the conjugate heat transfer approach, without modelling of the catalyst or nanotube particles, to optimize the gas phase reaction to synthesize CNT materials. Using CFD solvers such as Ansys-Fluent, the design of the reactor was modeled and modified in a comprehensive manner, ther (open full item for complete abstract)
Committee: Shaaban Abdallah Ph.D. (Committee Member); Mark Schulz Ph.D. (Committee Member); Kelly Cohen Ph.D. (Committee Member)
Subjects: Aerospace Materials