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Towards Achieving Higher Product Selectivity by Controlling Photoreactivity

George, Sobiya
http://rave.ohiolink.edu/etdc/view?acc_num=ucin1636388816044967

Abstract Details

2021, PhD, University of Cincinnati, Arts and Sciences: Chemistry.
The outline of this dissertation is achieving higher selectivity by controlling the photoreactivity. We report the selective formation of the targeted photoproducts by controlling the photoreactivity of 2-hydroxy chalcone derivatives as well as different types of organic azides. In addition, we explored the photoreactivity under continuous flow method and in cryogenic matrices as well. Below is a summary of the research projects explored and studied in this dissertation, ?
Anna Gudmundsdottir, Ph.D. (Committee Chair)
James Mack (Committee Member)
Ruxandra Dima, Ph.D. (Committee Member)
321 p.
Chemistry
The stability of triplet vinylnitrenes from isoxazoles under cryogenic temperature. These triplet vinylnitrenes are flexible at cryogenic temperatures and forms the corresponding ketenimine. The flexibility of the vinylic double bond facilitates the intersystem crossing of the triplet vinylnitrenes to form the products. The stability of the triplet

Recommended Citations

Citations

  • George, S. (2021). Towards Achieving Higher Product Selectivity by Controlling Photoreactivity [Doctoral dissertation, University of Cincinnati]. OhioLINK Electronic Theses and Dissertations Center. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1636388816044967

    APA Style (7th edition)

  • George, Sobiya. Towards Achieving Higher Product Selectivity by Controlling Photoreactivity. 2021. University of Cincinnati, Doctoral dissertation. OhioLINK Electronic Theses and Dissertations Center, http://rave.ohiolink.edu/etdc/view?acc_num=ucin1636388816044967.

    MLA Style (8th edition)

  • George, Sobiya. "Towards Achieving Higher Product Selectivity by Controlling Photoreactivity." Doctoral dissertation, University of Cincinnati, 2021. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1636388816044967

    Chicago Manual of Style (17th edition)

ucin1636388816044967
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This open access ETD is published by University of Cincinnati and OhioLINK.