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Novel Dinucleating Poly(oxime) Amine Ligands and their Nickel and Zinc Complexes: Oxygen and Hydrolysis Reactivity

DETERS, ELIZABETH ANN
http://rave.ohiolink.edu/etdc/view?acc_num=ucin1180644861

Abstract Details

2007, PhD, University of Cincinnati, Arts and Sciences : Chemistry.
A series of mononuclear poly(oxime) amine nickel(II) complexes has been shown to catalyze the oxidation of various substances. To further this work, a series of novel dinucleating ploy(oxime) amine ligands and their nickel complexes were synthesized. During this synthesis, a novel anion dependence on the nuclearity of the complex was discovered and investigated for two of the ligands. All of the dinuclear complexes were shown to catalyze the oxidation of various substances, including methanol, benzyl alcohol, and benzylamine. In addition to the oxygen reactivity, zinc complexes of the poly(oxime) amine ligands were shown to have hydrolysis reactivity. These complexes successfully catalyzed the hydrolysis of p-nitrophenyl acetate. Some preliminary kinetic data for the reaction was also obtained.
Dr. Michael Baldwin (Advisor)
120 p.
Chemistry, Inorganic
nickel; dinuclear; oxime; zinc; hydrolysis

Recommended Citations

Citations

  • DETERS, E. A. (2007). Novel Dinucleating Poly(oxime) Amine Ligands and their Nickel and Zinc Complexes: Oxygen and Hydrolysis Reactivity [Doctoral dissertation, University of Cincinnati]. OhioLINK Electronic Theses and Dissertations Center. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1180644861

    APA Style (7th edition)

  • DETERS, ELIZABETH. Novel Dinucleating Poly(oxime) Amine Ligands and their Nickel and Zinc Complexes: Oxygen and Hydrolysis Reactivity. 2007. University of Cincinnati, Doctoral dissertation. OhioLINK Electronic Theses and Dissertations Center, http://rave.ohiolink.edu/etdc/view?acc_num=ucin1180644861.

    MLA Style (8th edition)

  • DETERS, ELIZABETH. "Novel Dinucleating Poly(oxime) Amine Ligands and their Nickel and Zinc Complexes: Oxygen and Hydrolysis Reactivity." Doctoral dissertation, University of Cincinnati, 2007. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1180644861

    Chicago Manual of Style (17th edition)

ucin1180644861
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© 2007, all rights reserved.
This open access ETD is published by University of Cincinnati and OhioLINK.
Release 3.2.12