Skip to Main Content
 

Global Search Box

 
 
 
 

Files

File List


Master thesis-Huang Xin.pdf (2.62 MB)

ETD Abstract Container

Abstract Header

SYNTHESIS AND CHARACTERIZATION OFSELF-ASSEMBLY BUILDING BLOCK CONTAINING PORPHYRIN RING AND BULKY BPOSS NANOPARTICLES

Huang, Xin
http://rave.ohiolink.edu/etdc/view?acc_num=akron1490477789132615

Abstract Details

2017, Master of Science, University of Akron, Polymer Science.
A series of precisely defined A-Cn -4B type shape amphiphilic giant molecule has been designed and synthesized by connecting one porphyrin as a core with four hydrophobic T8 polyhedral oligomeric silsesquioxane (BPOSS that represent all isobutyl groups functionalized POSS) via alkyl chain(n= 0,1,10). Here, porphyrin can afford powerful pi- pi interaction, meanwhile variation of the length linker such as zero, one, ten carbon atoms offering mobility during self-assembling, and furthermore bulky BPOSS nanoparticles could form the periphery of the giant molecule to introduce steric hinderer and hydrophobic interactions. With synergistic interactions from porphyrin, different linker length and bulky POSS nanoparticles, various supramolecular structures are expected to be formed. Here, shape amphiphilic giant molecules are designed and synthesized, to research on the influence of the linker length on the final supramolecular structures and the corresponding formation mechanism to form Frank-Kasper phases
Toshikazu Miyoshi (Advisor)
Stephen Z.D. Cheng (Committee Member)
57 p.
Organic Chemistry; Polymer Chemistry
POSS nanoparticles; porphyrin ring; self-assembly; pi-pi interaction, steric interaction; length linker

Recommended Citations

Citations

  • Huang, X. (2017). SYNTHESIS AND CHARACTERIZATION OFSELF-ASSEMBLY BUILDING BLOCK CONTAINING PORPHYRIN RING AND BULKY BPOSS NANOPARTICLES [Master's thesis, University of Akron]. OhioLINK Electronic Theses and Dissertations Center. http://rave.ohiolink.edu/etdc/view?acc_num=akron1490477789132615

    APA Style (7th edition)

  • Huang, Xin. SYNTHESIS AND CHARACTERIZATION OFSELF-ASSEMBLY BUILDING BLOCK CONTAINING PORPHYRIN RING AND BULKY BPOSS NANOPARTICLES. 2017. University of Akron, Master's thesis. OhioLINK Electronic Theses and Dissertations Center, http://rave.ohiolink.edu/etdc/view?acc_num=akron1490477789132615.

    MLA Style (8th edition)

  • Huang, Xin. "SYNTHESIS AND CHARACTERIZATION OFSELF-ASSEMBLY BUILDING BLOCK CONTAINING PORPHYRIN RING AND BULKY BPOSS NANOPARTICLES." Master's thesis, University of Akron, 2017. http://rave.ohiolink.edu/etdc/view?acc_num=akron1490477789132615

    Chicago Manual of Style (17th edition)

akron1490477789132615
163
© 2017, all rights reserved.
This open access ETD is published by University of Akron and OhioLINK.
Release 3.2.12